By Derek Horton
Due to the fact that its inception in 1945, this serial has supplied severe and integrating articles written by way of examine experts that combine business, analytical, and technological features of biochemistry, natural chemistry, and instrumentation technique within the examine of carbohydrates. The articles supply a definitive interpretation of the present prestige and destiny traits in carbohydrate chemistry and biochemistry. prime quality entire stories masking all points of carbohydrate chemistry
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Additional info for Advances in Carbohydrate Chemistry and Biochemistry, Vol. 59
The accompanying molecule of pyridine is removed at 105 ◦ C. The ␤-d anomer is also prepared103 by crystallization from hot acetic acid and recrystallization from water and alcohol. At temperatures above 115 ◦ C, ␤-d-glucose is the stable form in contact with a saturated aqueous solution. 104 The commercial material known as glucose syrup is made by autoclaving aqueous starch suspensions with acid. It usually has a reducing power in the range of 40–45% of the same weight of d-glucose; the concentration of solid material lies in the range of 78–85%.
The 24 r. m. de lederkremer and c. gallo-rodriguez branch points act as a barrier during sacchariﬁcation by glucoamylases, which hydrolyze (1→6) linkages at a low rate. The sacchariﬁcation reaction can be improved by incorporating a speciﬁc debranching enzyme, such as pullulanase or isoamylase, into the system. The glucoamylase requirement is decreased because this enzyme has only to hydrolyze the ␣-(1→4)-d-glucosidic linkages. 100 The use of cellulosic wastes for the production of glucose is of commercial interest, and in consequence much research work has been done on the characterization of cellulases.
86 This monosaccharide is present only in the pyranose form in the mammalian oligosaccharides. However, 22 r. m. de lederkremer and c. 87 Preparation. The method most frequently used involves the hydrolysis of lactose by acids, and fractional crystallization of the d-galactose liberated. A modiﬁcation of the method entails removal of the d-glucose by fermentation with yeasts, and crystallization of the d-galactose remaining. 88 The crystalline sugar is usually encountered as ␣-d-galactopyranose, although the ␤-d anomer is obtained by crystallization from cold, alcoholic solution.
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