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By R J Ferrier, R Blattner, O McDonald, R H Furneaux, P C Tyler, R H Wightman, K Clinch, J M Gardiner, R A Field, K P R Kartha, D M G Tilbrook

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S. T. Hagler, Biopofymers, 1998,45,435 (Chern. , 1998,128,308 655). D. A. E. W. Brown, J. Phys. Chern. A , 1998, 102,5086 (Chem. , 1998, 129,28 122). J. Mazurkiewicz, Pol. J. Food Nutr. , 1997, 6, 35 (Chem. , 1998, 128, 205 058). G. Zubay, Origins Life Evol. Biosphere, 1998, 28, 13 (Chem. , 1998, 128, 282 983). S. J. -H. Wong, Chem. , 1997, 26, 407 (Chem. , 1998,128, 128 183). C. C. W. P. J. Toone, J. Chern. , Perkin Trans. I , 1998, 1335. M. Carrano and A. Vasella, Hefv. Chim. Acta, 1998,81,889.

Lo 30 29 X = H, Me, OMe, Br, CI n =2,3 R=H,Me f? QH 0 OH 31 Ten sulfated and three phosphorylated galactosyl compounds have been made as glycolipid analogues. Each contained two or three 0-P-D-galactopyranosyl derivatives of 2- C-alkylpropane-1,3-diol, 2,2-di-C-alkylpropane-1,3diol or 2-C-alkykl-3-C-(hydroxymethyl)butane1,4-diol. Special interest has been taken in compounds containing several a-D-mannose moieties: oligomannopeptoids based on oligoglycines carrying 2-(a-~-mannopyranosyloxyethyl) substituents on N;"* cluster compounds 32'l 3 and compounds derived by extension as indicated in 33.

Daniel, Carbohydr. W. Lichtenthaler, Carbohydr. , 1998,313,69. K. W. Frost, J. Am. Chem. , 1998,120, 10545. J. Koch, M. Pischetsrieder, K. Polborn and T. Severin, Carbohydr. , 1998, 49 50 51 52 1998,310, 15 1. 313, 117. T. Hofmann, Carbohydr. , 1998,313,203. T. Hofmann, Carbohydr. , 1998,313,215. H. M. Ansari, J. Chem. SOC. , 1997,19,221 (Chem. , 1998,128, 180 586). J. J. J. J. Freudigmann, Tetrahedron, 1997, 53, 3669. 53 Y. Shigemasa, N. Tereda, T. Mori, M. Morimoto, H. Sashiwa and H. Saimoto, Bull.

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